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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Cyclopentadienylcobalt dicarbonyl ： ウィキペディア英語版 Cyclopentadienylcobalt dicarbonyl |Section2= |Section3= }} Cyclopentadienylcobalt dicarbonyl is an organocobalt compound with formula (C5H5)Co(CO)2, abbreviated CpCo(CO)2. It is an example of a half-sandwich complex. It is a dark red air sensitive liquid. This compound features one cyclopentadienyl ring that is bound in an η5-manner and two carbonyl ligands. The compound is soluble in common organic solvents and it is best stored under nitrogen. ==Preparation== CpCo(CO)2 was first reported in 1954 by Piper, Cotton, and Wilkinson who produced it by the reaction of cobalt carbonyl with cyclopentadiene. It is prepared commercially by the same method: : Co2(CO)8 + 2 C5H6 → 2 C5H5Co(CO)2 + H2 + 4 CO Alternatively, it is generated by the high pressure carbonylation of bis(cyclopentadienyl)cobalt (cobaltocene) at elevated temperature and pressures: :Co(C5H5)2 + 2 CO → C5H5Co(CO)2 + "C5H5" 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Cyclopentadienylcobalt dicarbonyl」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.